Sending an SMS on new order placed – WooCommerce

I want to send SMS while new order gets placed, now I have used woocommerce_order_status_completed hook, but this only works while you move order processing to complete.
Alternatively, I have also used woocommerce_order_status_processing but it’s also not working.

So the question is can I send SMS at the same time while the order getting placed?
Note: SMS are working fine here